Underwater acoustic communication is heavily influenced by intersymbol interference caused by the delay spread of multipaths. In this article, communication sequences transmitted from a drifting source were received by a fixed acoustic vector receiver system consisting of an accelerometer-based vector sensor and a pressure sensor, which can measure the three-directional components of vector quantity and pressure at a point. The underwater acoustic communication experiment was conducted in water approximately 30 m deep off the south coast of Geoje Island, South Korea, in May 2017 during the Korea Reverberation Experiment. Acceleration signals received by the vector sensor were converted to pressure-equivalent particle velocities, which were then used as input for a four-channel communication system together with acoustic pressure. These four channels have multipaths with different amplitudes but the same delay times, providing directional diversity that differs from the spatial diversity provided by hydrophone arrays. To improve the communication performance obtained from directional diversity, the Multichannel Combined Bidirectional Block-based Time Reversal Technique was used, which combines bidirectional equalization with time-reversal diversity and block-based time reversal that was robust against time-varying channels. Communication performance was compared with the outcomes produced by several other time reversal techniques. The results show that the Multichannel Combined Bidirectional Block-based Time Reversal Technique using a vector sensor achieved superior performance under the environmental conditions considered in this article.