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·인용수 22
·2025
Localized Eutectic Electrolytes for Stable Aqueous Zinc-Ion Batteries
Huida Lyu, Jung Tae Kim∥, Dongfang Cheng, Xintong Yuan, Mackenzie Anderson, Keyue Liang, Jiayi Yu, Philippe Sautet, Richard B. Kaner, Yuzhang Li
IF 18.2ACS Energy Letters
초록

Aqueous zinc-ion batteries (AZIBs) have been regarded as promising candidates for large-scale energy storage. However, the poor reversibility of Zn electrodeposition at low current densities still remains a great challenge in developing practical AZIBs. In this work, a localized eutectic electrolyte (LEE) is proposed by introducing trioxane to a baseline eutectic electrolyte, 2.0 M Zn-(OTf)<sub>2</sub> in water/sulfolane (50:50 vol %), for reversible Zn anodes under challenging conditions (low N/P ratios and low current densities). Trioxane serves to disperse the aqueous eutectic domain and construct a solvation-sheath-repelled inner Helmholtz plane, thus regulating charge transfer kinetics to enable further suppression of electrolyte corrosion and improved Zn morphology. Zn||Zn<sub>0.25</sub>V<sub>2</sub>O<sub>5</sub>·<i>n</i>H<sub>2</sub>O full cells with a low N/P ratio (≤4) and a low current density of 100 mA cathode<sup>-1</sup> (corresponding to a 0.33 C rate) exhibit enhanced cycling stability and a prolonged lifespan (nearly 3 months) in the LEE.

키워드
Eutectic systemElectrolyteAqueous solutionZincIonMaterials scienceChemical engineeringInorganic chemistryMetallurgyChemistry
타입
article
IF / 인용수
18.2 / 22
게재 연도
2025

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