기본 정보
연구 분야
프로젝트
논문
구성원
preprint|
green
·인용수 0
·2025
Temperature- and charge carrier density-dependent electronic response in methylammonium lead iodide
Jiacheng Wang Jungmin Park, Lei Gao, Lucia Di Virgilio, Sheng Qu, Heejae Kim, Hai I. Wang, Liangcai Wu, Wen Zeng, Mischa Bonn, Zefeng Ren, Jaco J. Geuchies
ArXiv.org
초록

Understanding carrier dynamics in photoexcited metal-halide perovskites is key for optoelectronic devices such as solar cells (low carrier densities) and lasers (high carrier densities). Trapping processes at low carrier densities and many-body recombination at high densities can significantly alter the dynamics of photoexcited carriers. Combining optical-pump/THz probe and transient absorption spectroscopy we examine carrier responses over a wide density range (10^14-10^19 cm-3) and temperatures (78-315K) in the prototypical methylammonium lead iodide perovskite. At densities below ~10^15 cm-3 (room temperature, sunlight conditions), fast carrier trapping at shallow trap states occurs within a few picoseconds. As excited carrier densities increase, trapping saturates, and the carrier response stabilizes, lasting up to hundreds of picoseconds at densities around ~10^17 cm-3. Above 10^18 cm-3 a Mott transition sets in: overlapping polaron wavefunctions lead to ultrafast annihilation through an Auger recombination process occurring over a few picoseconds. We map out trap-dominated, direct recombination-dominated, and Mott-dominated density regimes from 78-315 K, ultimately enabling the construction of an electronic phase diagram. These findings clarify carrier behavior across operational conditions, aiding material optimization for optoelectronics operating in the low (e.g. photovoltaics) and high (e.g. laser) carrier density regimes.

키워드
Charge carrierPicosecondAuger effectCarrier lifetimePhotoexcitationTrappingUltrafast laser spectroscopyPolaronExcited state
타입
preprint
IF / 인용수
- / 0
게재 연도
2025

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