The purpose of this study is to investigate the distribution of VOCs concentration in the residential area of Yeosu Petrochemical Industrial Complex. VOCs measuring point is Jusam-dong, located about 1.5 km south of Yeosu National Industrial Complex. It was measured continuously for 7 days in each season by collecting twice a day for four seasons. VOCs were measured during four seasons in order to understand the characteristics of atmospheric VOCs concentration in Jusam-dong, a residential area near the Yeosu Petrochemical Industrial Complex. The mean concentrations of toluene, ethylbenzene, m,p-xylene, o-xylene and styrene were detected 100%, benzene 98%. The mean concentrations were hexane 0.93 ppb > toluene 0.81 ppb > benzene 0.63 ppb > 1,2-dichloroethane 0.49 ppb. The Seasonal concentration were low in spring and summer, and high in fall and winter. During the daytime and during the afternoon, the daytime concentration was higher than in the afternoon. The correlations between VOCs components were highly correlated with each other. Also there was a significant positive correlation with NO2, CO, and SO2 among air quality parameters. Compared with previous studies on other industrial complexes, the Jusam-dong site had higher concentrations of benzene than other regions, but other materials were generally low or similar.