The recognition capability of the identification system using Raman spectroscopy is increasing with the demands in the field. Among the various approaches that determine the identity of a target, signal correlation using a moving window is one of the most effective and intuitive methods. In this paper, we report a new correlation method that is robust to spectral intensity variations. Using the peak distribution of a given spectrum, this method adaptively determines meaningful spectral regions for the identification target. Three commercial Raman spectrometer and a 14 033 library were included in the study, which was used for a library-based chemical discrimination test and mixed material analysis experiments. According to the identification experimental results, the proposed method correctly identified all of the spectra and maintained a mean correlation score above 0.95 while maintaining the correlation score of nontarget materials as low as possible.