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연구 분야
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구성원
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hybrid
·인용수 2
·2025
Enhancing visible-light-driven photocatalysis of Pd- and Pt-doped WO3 nanoparticles: the role of oxygen vacancies and bandgap narrowing
Hyeri Jeon, Dung Thanh Hoang, Hyejin Yu, Sun-Young Hwang, Hyun Sung Kim, Seungwoo Hong, Hangil Lee
IF 3.3Dalton Transactions
초록

The global energy demand has driven the development of efficient and cost-effective visible-light-activated photocatalysts for the synthesis of fine chemicals. However, most high-performance photocatalysts possess bandgaps exceeding ∼3.0 eV, limiting their photocatalytic efficiency under visible light. In this study, Pd- and Pt-doped WO<sub>3</sub> nanoparticles were synthesized. Doping induced oxygen vacancies, which act as electron traps, reducing the bandgap and enhancing visible-light-driven photocatalytic activity. The photocatalytic performance was examined using hydroxymethylfurfural and benzyl alcohol as model substrates. The product yields for both substrates in the presence of Pd-doped WO<sub>3</sub> nanoparticles exceeded 95%. This work demonstrates a simple strategy for enhancing the solar-energy-driven photocatalytic efficiency of metal oxide nanoparticles, promoting sustainable fine chemical synthesis.

키워드
PhotocatalysisDopingVisible spectrumMaterials scienceBand gapOxygenNanoparticlePhotochemistryNanotechnologyCatalysis
타입
article
IF / 인용수
3.3 / 2
게재 연도
2025

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