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·2025
Laser-induced graphene as a versatile platform for colloidal quantum dot heterostructure photodetectors
Jiyoon Oh, Donggu Lee, Kyoungeun Lee, Yeyun Bae, Jaeyeop Lee, Young Jae Kim, Byeong Guk Jeong, Jaehoon Kim, Hanchul Cho, Jeongkyun Roh
IF 4.6RSC Advances
초록

The growing demand for high-performance, flexible, and low-cost photodetectors has driven research interest in heterostructure-based architectures that integrate materials with complementary optical and electronic properties. In this study, we developed a heterostructure photodetector platform based on laser-induced graphene (LIG) and lead sulfide colloidal quantum dots (QDs). LIG, which is directly patterned on polyimide <i>via</i> laser irradiation, offers scalable mask-free fabrication with mechanical flexibility and excellent conductivity. To enhance charge transfer between the QDs and LIG, solid-state ligand exchange was performed, replacing the long-chain oleic acid ligands with short iodide ligands. This modification significantly improved charge transfer efficiency, resulting in a high photo-to-dark current ratio (>100), responsivity approximately 20 A W<sup>-1</sup> with excellent linearity across a wide range of light intensities, and specific detectivity exceeding 10<sup>11</sup> Jones. Furthermore, the versatility of LIG formation was demonstrated through its compatibility with various polyimide substrate formats, proving its potential for fabricating flexible, large-area, and customizable electrode patterns. These findings highlight the application potential of LIG-QD heterostructures as a platform for next-generation flexible optoelectronic devices.

키워드
PhotodetectorHeterojunctionGrapheneQuantum dotResponsivityPolyimideFabricationElectrodeResistive touchscreen
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article
IF / 인용수
4.6 / 0
게재 연도
2025