Owing to their large ratio of surface area to mass and volume, metal-organic frameworks and porous carbons have revolutionized many applications that rely on chemical and physical interactions at surfaces. However, a major challenge today is to shape these porous materials to translate their enhanced performance from the laboratory into macroscopic real-world applications. In this review, we give a comprehensive overview of how the precise morphology control of metal oxides can be transferred to metal-organic frameworks and porous carbon materials. As such, tailored material structures can be designed in 0D, 1D, 2D, and 3D with considerable implications for applications such as in energy storage, catalysis and nanomedicine. Therefore, we predict that major research advances in morphology control of metal-organic frameworks and porous carbons will facilitate the use of these materials in addressing major needs of the society, especially the grand challenges of energy, health, and environment.

A noncarbonaceous material (titanium nitride, TiN) with well-defined multiscale porous architecture is easily developed by multiscale phase separation and applied as a sulfur host for lithium–sulfur batteries, as described by Jinwoo Lee and co-workers in article number 1806547. The synergistic effect between the unique porous architecture and surface chemical properties of TiN enables ultrastable, high-rate lithium–sulfur batteries.

Porous architectures are important in determining the performance of lithium-sulfur batteries (LSBs). Among them, multiscale porous architecutures are highly desired to tackle the limitations of single-sized porous architectures, and to combine the advantages of different pore scales. Although a few carbonaceous materials with multiscale porosity are employed in LSBs, their nonpolar surface properties cause the severe dissolution of lithium polysulfides (LiPSs). In this context, multiscale porous structure design of noncarbonaceous materials is highly required, but has not been exploited in LSBs yet because of the absence of a facile method to control the multiscale porous inorganic materials. Here, a hierarchically porous titanium nitride (h-TiN) is reported as a multifunctional sulfur host, integrating the advantages of multiscale porous architectures with intrinsic surface properties of TiN to achieve high-rate and long-life LSBs. The macropores accommodate the high amount of sulfur, facilitate the electrolyte penetration and transportation of Li⁺ ions, while the mesopores effectively prevent the LiPS dissolution. TiN strongly adsorbs LiPS, mitigates the shuttle effect, and promotes the redox kinetics. Therefore, h-TiN/S shows a reversible capacity of 557 mA h g^-1 even after 1000 cycles at 5 C rate with only 0.016% of capacity decay per cycle.

Mesoporous inorganic particles and hollow spheres are of increasing interest for a broad range of applications, but synthesis approaches are typically material specific, complex, or lack control over desired structures. Here it is reported how combining mesoscale block copolymer (BCP) directed inorganic materials self-assembly and macroscale spinodal decomposition can be employed in multicomponent BCP/hydrophilic inorganic precursor blends with homopolymers to prepare mesoporous inorganic particles with controlled meso- and macrostructures. The homogeneous multicomponent blend solution undergoes dual phase separation upon solvent evaporation. Microphase-separated (BCP/inorganic precursor)-domains are confined within the macrophase-separated majority homopolymer matrix, being self-organized toward particle shapes that minimize the total interfacial area/energy. The pore orientation and particle shape (solid spheres, oblate ellipsoids, hollow spheres) are tailored by changing the kind of homopolymer matrix and associated enthalpic interactions. Furthermore, the sizes of particle and hollow inner cavity are tailored by changing the relative amount of homopolymer matrix and the rates of solvent evaporation. Pyrolysis yields discrete mesoporous inorganic particles and hollow spheres. The present approach enables a high degree of control over pore structure, orientation, and size (15-44 nm), particle shape, particle size (0.6-3 µm), inner cavity size (120-700 nm), and chemical composition (e.g., aluminosilicates, carbon, and metal oxides).

Owing to their large ratio of surface area to mass and volume, metal-organic frameworks and porous carbons have revolutionized many applications that rely on chemical and physical interactions at surfaces. However, a major challenge today is to shape these porous materials to translate their enhanced performance from the laboratory into macroscopic real-world applications. In this review, we give a comprehensive overview of how the precise morphology control of metal oxides can be transferred to metal-organic frameworks and porous carbon materials. As such, tailored material structures can be designed in 0D, 1D, 2D, and 3D with considerable implications for applications such as in energy storage, catalysis and nanomedicine. Therefore, we predict that major research advances in morphology control of metal-organic frameworks and porous carbons will facilitate the use of these materials in addressing major needs of the society, especially the grand challenges of energy, health, and environment.

A noncarbonaceous material (titanium nitride, TiN) with well-defined multiscale porous architecture is easily developed by multiscale phase separation and applied as a sulfur host for lithium–sulfur batteries, as described by Jinwoo Lee and co-workers in article number 1806547. The synergistic effect between the unique porous architecture and surface chemical properties of TiN enables ultrastable, high-rate lithium–sulfur batteries.

Porous architectures are important in determining the performance of lithium-sulfur batteries (LSBs). Among them, multiscale porous architecutures are highly desired to tackle the limitations of single-sized porous architectures, and to combine the advantages of different pore scales. Although a few carbonaceous materials with multiscale porosity are employed in LSBs, their nonpolar surface properties cause the severe dissolution of lithium polysulfides (LiPSs). In this context, multiscale porous structure design of noncarbonaceous materials is highly required, but has not been exploited in LSBs yet because of the absence of a facile method to control the multiscale porous inorganic materials. Here, a hierarchically porous titanium nitride (h-TiN) is reported as a multifunctional sulfur host, integrating the advantages of multiscale porous architectures with intrinsic surface properties of TiN to achieve high-rate and long-life LSBs. The macropores accommodate the high amount of sulfur, facilitate the electrolyte penetration and transportation of Li⁺ ions, while the mesopores effectively prevent the LiPS dissolution. TiN strongly adsorbs LiPS, mitigates the shuttle effect, and promotes the redox kinetics. Therefore, h-TiN/S shows a reversible capacity of 557 mA h g^-1 even after 1000 cycles at 5 C rate with only 0.016% of capacity decay per cycle.

Mesoporous inorganic particles and hollow spheres are of increasing interest for a broad range of applications, but synthesis approaches are typically material specific, complex, or lack control over desired structures. Here it is reported how combining mesoscale block copolymer (BCP) directed inorganic materials self-assembly and macroscale spinodal decomposition can be employed in multicomponent BCP/hydrophilic inorganic precursor blends with homopolymers to prepare mesoporous inorganic particles with controlled meso- and macrostructures. The homogeneous multicomponent blend solution undergoes dual phase separation upon solvent evaporation. Microphase-separated (BCP/inorganic precursor)-domains are confined within the macrophase-separated majority homopolymer matrix, being self-organized toward particle shapes that minimize the total interfacial area/energy. The pore orientation and particle shape (solid spheres, oblate ellipsoids, hollow spheres) are tailored by changing the kind of homopolymer matrix and associated enthalpic interactions. Furthermore, the sizes of particle and hollow inner cavity are tailored by changing the relative amount of homopolymer matrix and the rates of solvent evaporation. Pyrolysis yields discrete mesoporous inorganic particles and hollow spheres. The present approach enables a high degree of control over pore structure, orientation, and size (15-44 nm), particle shape, particle size (0.6-3 µm), inner cavity size (120-700 nm), and chemical composition (e.g., aluminosilicates, carbon, and metal oxides).

In article number 1801127, Jinwoo Lee and co-workers transfer insights from the physics of polymer blends to materials synthesis and thus develop a facile yet versatile strategy, namely, spherical and hollow assembly-based particle engineering (SHAPE), which opens a new avenue for the synthesis of mesoporous inorganic particles (oblate ellipsoids, solid spheres) and hollow spheres with unprecedentedly high level of structure control.

Two-dimensional covalent organic frameworks (2D COFs) are emerging as promising materials for advanced electronic applications due to their tunable porosity, crystalline order, and π-conjugated structures. These properties enable efficient charge transport and bandgap modulation, making 2D COFs strong candidates for electronic devices such as transistors and memristors. However, the practical application of COFs remains limited by challenges in achieving high-quality thin films with large-area uniformity and improved crystallinity. This review explores recent advancements in the fabrication and application of conductive 2D COFs for electronics. Various synthesis strategies, including direct growth, vapor-assisted conversion, and interfacial methods, are discussed in the context of enhancing film quality and scalability. The integration of COFs into electronic devices is classified based on their operation mechanism─planar and vertical field-effect transistors (FETs), electrochemical transistors (ECTs), and memristors─to highlight their electronic properties and device performance. Looking forward, the challenges of large-scale production, material compatibility, and device integration are outlined, alongside potential solutions through innovative synthesis techniques and collaborative research efforts. By addressing these challenges, 2D COFs are poised to drive breakthroughs in electronic devices by their adoption in next-generation semiconducting technologies.

Hybrid Supercapacitors In article number 2410010, Eunho Lim, Jongkook Hwang, and co-workers report on mesoporous carbon spheres with a controlled degree of mesopore openings achieved through multiscale phase separation. The study demonstrates that opening mesopores enhances the accessibility of active sites and facilitates more efficient ion transport, ultimately improving the power density of potassium-ion storage.

This review explores how nanochannel membranes advance SED by improving ion selectivity and separation performance.