In‐Cavity Lithium Deposition Enabled by Carbon Framework‐Integrated Separator for Stable Low‐Pressure Cycling
J.S. Park, Hyungoo Shin, Seung Jong Lee, Seongmin Ha, Jongchan Song, Jong‐Won Lee
IF 12.1
Small
Practical implementation of Li metal anodes has been hindered by non-uniform, dendritic growth of Li, which causes continuous side reactions, internal short-circuiting, and early cell failure. Although applying external pressure has been reported to promote dense Li plating to some extent, the practical application of this approach remains limited. Herein, a carbon framework-integrated separator to regulate the plating-stripping behavior of Li at reduced external pressure is proposed. To ensure both high porosity and mechanical integrity, carbon nanofibers (CNFs) are employed as a model material for realizing the framework-integrated separator structure. CNFs are electrophoretically deposited onto the separator to achieve a uniform and mechanically robust layer, while preserving the intrinsic porous structure of the separator. Combined experimental and computational studies show that when assembled with a Li metal anode, the carbon framework-integrated separator enables kinetics-controlled "in-cavity" deposition, effectively guiding dense Li plating and accommodating plating-induced volume changes. As a result, a high-voltage (4.25 V) and high-capacity (4.0 mAh cm<sup>-2</sup>) full cell exhibits stable cycling under low external pressure (0.26 MPa). This work provides a promising strategy for designing functional separators to realize practical high-energy-density Li metal batteries.
Analysis of Air Diffusion Performance Index of Fixed Vane Air Supply Type Ventilation System by Real Space Experiment
Il Yeong Oh, J.S. Park, Wonseok Oh, Jinkyun Cho, Beungyong Park
Korean Journal of Air-Conditioning and Refrigeration Engineering
This study examined the potential of using a ductless, fixed vane air supply type ventilation system as a solution to structural and cost limitations of duct-type systems in aging buildings. The performance of such ductless, fixed vane air supply type ventilation system was evaluated based on air delivery, indoor airflow distribution, and thermal comfort. Measurements showed a turbulence intensity of 4% at the diffuser outlet, with an average velocity of 2.69 m/s and a velocity standard deviation of 0.12 m/s, indicating a stable airflow. Airflow distribution results revealed velocities between 0.05 m/s and 0.3 m/s, providing a stable and imperceptible draft sensation for seated and standing occupants. The system maintained effective air delivery up to 8 m from the diffuser, achieving uniform air distribution throughout the space. Effective Draft Temperature (EDT) analysis confirmed that airflow and temperature variations remained within the ADPI comfort zone. These findings demonstrate that ductless, fixed vane air supply systems can effectively address limitations of ducted systems while ensuring thermal comfort. This study provides a practical framework for implementing cost-effective and efficient ventilation solutions in aging buildings.
High-Precision Softmax Division without Multipliers or Look-Up Tables
J.S. Park, Chae Eun Rhee
Softmax plays a critical role in deep learning accelerators, but its hardware implementations often suffer from precision loss due to inaccurate division operations. This paper focuses on the design of a high-precision division unit for Softmax, introducing a three-segment piecewise approximation of 1+s1 that effectively reduces approximation errors. The proposed approach improves numerical accuracy over previous designs, while preserving hardware efficiency and maintaining a multiplication-free and look-up table-free architecture.
Enhanced Cycling Stability of Li Metal Batteries under Reduced Pressure via Conductive Framework–Separator Integration
J.S. Park, Hong Rim Shin, Jongwon Lee
ECS Meeting Abstracts
Li ion batteries, widely used in electric vehicles and portable electronics, are now confronting theoretical thresholds in energy density due to low specific capacity of graphite anodes. One promising approach to boost energy density (> 400 Wh kg −1 ) is Li metal batteries (LMBs) paired with commercially available Ni-rich cathodes (LiNi x M 1−x O 2 , M=Mn, Co and x ≥ 0.6). Li metal anodes (LMAs) are regarded as an attractive candidate for next-generation anodes for high-energy-density energy storage because of their high specific capacity (3860 mAh g −1 ) and low electrochemical potential (−3.04 V vs. standard hydrogen electrode). However, the practical deployment of LMAs is hindered by their intrinsic high reactivity and uncontrollable growth of Li dendrites, which consequently lead to excessive parasitic reactions and short lifespan of batteries. Recent studies have demonstrated that applying external mechanical pressures to LMAs effectively suppresses dendritic Li growth, promoting dense and uniform Li deposition. Nevertheless, excessively high pressures (>10 MPa) inevitably lead to detrimental effects such as pore collapse in polyolefin separators and even mechanical tearing, ultimately causing internal short circuits. Three-dimensional (3D) frameworks, which have been extensively studied to resolve the critical issues of LMAs, can improve the cell performance of LMBs under low-pressure operation by providing abundant pore volume to accommodate volume expansion and regulate Li deposition behavior. Herein, we present a porous 3D framework of vapor-grown carbon fibers (VGCFs) integrated with the separator via electrophoretic deposition (EPD) to guide uniform Li + flux. By optimizing the EPD parameters, a mechanically robust and uniformly porous VGCF layer is combined with a commercial polypropylene (PP) separator. 3D electrochemical simulations reveal that the abundant Li⁺ transport pathways in the VGCF layer enable homogeneous Li⁺ distribution, which could inhibit formation and growth of Li dendrites. This prediction is validated through microstructural analysis of Li deposition, which confirms that Li metal is densely and uniformly deposited within the VGCF layer, gradually filling the pores in the framework from bottom to top. Electrochemical properties under reduced external pressure conditions further confirm the efficacy of the VGCF-integrated separator. Compared to bare PP, symmetric cells and half cells with VGCF-integrated separators exhibit more stable Li plating/stripping, featuring reduced hysteresis and improved reversibility. Notably, full cell employing high-voltage NCM cathode and VGCF-integrated separator maintains a capacity retention of 87.3% after 200 cycles, outperforming cells using bare PP. These results demonstrate that the VGCF-integrated separator enables reliable operation of LMBs under practical low-pressure conditions. This work provides a new approach for the design of advanced 3D frameworks for high-energy-density LMBs.for the design of advanced 3D frameworks for high-energy-density LMBs.
Feasibility study on predicting personal thermal comfort using EEG in dynamically changing thermal environments
J.S. Park, Doyun Lee, Jongseong Gwak, Wonseok Oh
Building Simulation Conference proceedings
Traditional thermal comfort models, such as the Predicted Mean Vote (PMV) model, estimate population-wide average comfort and overlook individual physiological differences. To address this, Personal Thermal Comfort (PTC) models incorporating physiological signals have been explored, with electroencephalography (EEG) gaining attention for its responsiveness to thermal perception and adaptation. This study analyzes EEG responses during thermal adaptation, distinguishing it from prior research focusing on stabilized conditions. EEG and skin temperature were measured under two thermal conditions, and Artificial Neural Networks (ANNs) were used to analyze EEG patterns. Results show significant individual variability, highlighting limitations of conventional models. Findings demonstrate that integrating EEG with environmental and physiological data enhances thermal comfort assessment accuracy, contributing to the development of a PTC model for real-time adaptive climate control in smart buildings and HVAC systems.
Improvement Methods of Horizontal Evacuation for Officetel Buildings considering Architectural Planning
Ho-Jeong Woo, Daniel Sang‐Hoon Lee, J.S. Park, Seong-hyeok Bae, You-Sik Lee, Yujin Nam
Korean Journal of Air-Conditioning and Refrigeration Engineering
Recently, officetel building fires are continuously occuring as the number of single-person households is increased. Since officetel buildings are designed with a focus on economics and sales, it is difficult to evacuate for occupants during fire events. Therefore, architectural plans are needed for evacuation of occupants in officetel buildings. This study aimed to propose improvement methods for horizontal evacuation in officetel buildings based on analysis results of domestic and international egress codes. Fire risk and horizontal evacuation performance were quantitatively evaluated using simulation models by comprehensively considering building materials, rooms, occupants, and fire characteristics of officetel. Architectural plans included width of corridor, width of exit door, and arrangement of exit based on building and egress regulations. Available safe egress time (ASET) was increased when corridor and exit door were wider and required safe egress time (RSET) was decreased due to elimination of bottlenecks. However, to ensure safe evacuation performance for occupants, widths of corridor and exit door need to be improved beyond building regulations. The central spaced arrangement was appropriate for center core type officetel buildings. The central spaced arrangement had a constant distance from all rooms, causing fewer bottlenecks than other arrangements.
In‐Cavity Lithium Deposition Enabled by Carbon Framework‐Integrated Separator for Stable Low‐Pressure Cycling
J.S. Park, Hyungoo Shin, Seung Jong Lee, Seongmin Ha, Jongchan Song, Jong‐Won Lee
IF 12.1
Small
Practical implementation of Li metal anodes has been hindered by non-uniform, dendritic growth of Li, which causes continuous side reactions, internal short-circuiting, and early cell failure. Although applying external pressure has been reported to promote dense Li plating to some extent, the practical application of this approach remains limited. Herein, a carbon framework-integrated separator to regulate the plating-stripping behavior of Li at reduced external pressure is proposed. To ensure both high porosity and mechanical integrity, carbon nanofibers (CNFs) are employed as a model material for realizing the framework-integrated separator structure. CNFs are electrophoretically deposited onto the separator to achieve a uniform and mechanically robust layer, while preserving the intrinsic porous structure of the separator. Combined experimental and computational studies show that when assembled with a Li metal anode, the carbon framework-integrated separator enables kinetics-controlled "in-cavity" deposition, effectively guiding dense Li plating and accommodating plating-induced volume changes. As a result, a high-voltage (4.25 V) and high-capacity (4.0 mAh cm<sup>-2</sup>) full cell exhibits stable cycling under low external pressure (0.26 MPa). This work provides a promising strategy for designing functional separators to realize practical high-energy-density Li metal batteries.