The key feature that enables soft sensors to shorten the performance gap between robots and biological structures is their deformability, coupled with their capability to measure physical changes. Robots equipped with these sensors can interact safely and proprioceptively with their environments. This has sparked interest in developing novel sensors with high stretchability for application in human-robot interactions. This study presents a novel ultrasoft optoelectronic segmented sensor design capable of measuring strains exceeding 500%. The sensor features an ultrastretchable segment physically joined with an asymmetrically configured soft proprioceptive segment. This configuration enables it to measure high strain and to detect both the magnitude and direction of bending. Although the sensor cannot decouple these types of deformations, it can sense prescribed motions that combine stretching and bending. The proposed sensor was applied to a highly deformable scissor mechanism and a human-robot interface (HRI) device for a robotic arm, capable of quantifying parameters in complex interactions. The results from the experiments also demonstrate the potential of the proposed segmented sensor concept when used in tandem with machine learning, affording new dimensions of proprioception to robots during multilayered interactions with humans.